A comparative study of side-band Fresnel holograms recorded with self-imaging and general objects

This paper deals with new results obtained in regard to the reconstruction properties of side-band Fresnel holograms (SBFH) of self-imaging type objects (for example, gratings) as compared with those of general objects. The major finding is that a distribution I₂, which appears on the real-image plane along with the conventional real-image I₁, remains a 2Z distribution (where 2Z is the axial distance between the object and its self-imaging plane) under a variety of situations, while its nature and focusing properties differ from one situation to another. It is demonstrated that the two distributions I₁ and I₂ can be used in the development of a novel technique for image subtraction.     

Elastic scattering and ω meson production near the threshold of π−p→ω+n

Measurements are reported of the differential cross section for the reaction π^?+p→ω+n from threshold to a final-state c.m. momentum $\text{P}{}^1\text{of}\text{200}\text{MeV}\text{/c}$. The previously reported fall in total cross section $\text{σ/P}{}^1$ below about 100 MeV/c is again seen. The differential cross section remains close to isotropic over the entire range. A paralle experiment on the variation in the elastic differential cross section across the threshold shows evidence of this threshold. The elastic data cover a range of incident moments from 1010 to 1180 MeV/c in steps of 5 MeV/c.     

An unusual cleavage of a side chain during catalytic hydrogenation of some octalones

Novel hydrogenolysis of a CC bond linking a benzyl side chain in some octalones is described.     

Studies on the extraction of vanadium (IV) in the presence of some anions and neutral oxygen donors

Extraction of vanadium (IV) in the presence of perchlorate, nitrate, halides, and thiocyanate and neutral oxygen donors liken-butanol, TBP and antipyrine into various solvents is studied. Composition of the extracting species and the stability constants are determined. The effectiveness of the three neutral oxygen donors studied in the extraction of vanadium (IV)-anion systems is found to follow the order: antipyrine > TBP >n-butanol.     

Premicellar and micelle formation behavior of aqueous anionic surfactants in the presence of triphenylmethane dyes: protonation of dye in ion pair micelles

The premicellar and micelle formation behaviors of four cationic triphenylmethane dyes, viz, Pararosaniline (RN), Crystal violet (CV), Ethyl violet (EV), and Malachite green (MG), in aqueous anionic surfactant solutions of sodium dodecyl sulfate (SDS), sodium dodecyl benzene sulfonate (SDBS), and sodium dodecyl sulfonate (SDSN) have been studied by spectral and surface tension measurements. The study was carried out within a pH range where the dyes are stable in their quinoid forms. The dyes have been found to form dye–surfactant ion pairs (DSIPs) with the surfactants, at the surfactant concentrations well below their critical micelle concentration, CMC*. The DSIPs behave like nonionic surfactants and form an air–water interfacial monolayer. The DSIPs have a lower critical micelle concentration (CMC_IP), greater efficiency, and lower effectiveness than the corresponding pure surfactants. As the surfactant concentration is increased below the CMC*, the DSIPs start forming micelles of their own where the dye gets protonated and exists as a protonated dye–surfactant ion pair (PDSIP) in the ion pair micelles. As the concentration of the surfactant exceeds the CMC* of the pure surfactant, the protonation reverses gradually with the dye remaining in the micelles in solubilized form and the DSIPs in the air–water interfacial monolayer are replaced by pure surfactants. The distorted helical isomeric form (isomer B) of the dyes is favored in the PDSIPs. Copyright © 2009 John Wiley & Sons, Ltd.     

Probing the formation mechanism and chemical states of carbon-supported Pt-Ru nanoparticles by in situ X-ray absorption spectroscopy

The understanding of the formation mechanism of nanoparticles is essential for the successful particle design and scaling-up process. This paper reports findings of an X-ray absorption spectroscopy (XAS) investigation, comprised of X-ray absorption near-edge structure (XANES) and extended X-ray absorption fine structure (EXAFS) regions, to understand the mechanism of the carbon-supported Pt-Ru nanoparticles (NPs) formation process. We have utilized Watanabe's colloidal reduction method to synthesize Pt-Ru/C NPs. We slightly modified the Watanabe method by introducing a mixing and heat treatment step of Pt and Ru oxidic species at 100 degrees C for 8 h with a view to enhance the mixing efficiency of the precursor species, thereby one can achieve improved homogeneity and atomic distribution in the resultant Pt-Ru/C NPs. During the reduction process, in situ XAS measurements allowed us to follow the evolution of Pt and Ru environments and their chemical states. The Pt LIII-edge XAS indicates that when H2PtCl6 is treated with NaHSO3, the platinum compound is found to be reduced to a Pt(II) form corresponding to the anionic complex [Pt(SO3)4]6-. Further oxidation of this anionic complex with hydrogen peroxide forms dispersed [Pt(OH)6]2- species. Analysis of Ru K-edge XAS results confirms the reduction of RuIIICl3 to [RuII(OH)4]2- species upon addition of NaHSO3. Addition of hydrogen peroxide to [RuII(OH)4]2- causes dehydrogenation and forms RuOx species. Mixing of [Pt(OH)6]2- and RuOx species and heat treatment at 100 degrees C for 8 h produced a colloidal sol containing both Pt and Ru metallic as well as ionic contributions. The reduction of this colloidal mixture at 300 degrees C in hydrogen atmosphere for 2 h forms Pt-Ru nanoparticles as indicated by the presence of Pt and Ru atoms in the first coordination shell. Determination of the alloying extent or atomic distribution of Pt and Ru atoms in the resulting Pt-Ru/C NPs reveals that the alloying extent of Ru (JRu) is greater than that of the alloying extent of Pt (JPt). The XAS results support the Pt-rich core and Ru-rich shell structure with a considerable amount of segregation in the Pt region and with less segregation in the Ru region for the obtained Pt-Ru/C NPs.     

Ultrafast all-optical XOR logic gate based on a symmetrical Mach-Zehnder interferometer employing SOI waveguides

We present an integrated Silicon-on-Insulator (SOI) based Mach-Zehnder interferometer (MZI) in order to perform ultrafast all-optical XOR logic gate operation with a bit rate of ∼ 0.33 Tb/s. A numerical simulation is carried out in order to study various parameters such as extinction ratio and eye-opening parameters, characterizing the performance of the XOR logic gate. The output XOR logic gate signal can have improved extinction and eye margin if the initial powers of primary signals and the probe continuous-wave (CW), and SOI waveguide length are judiciously adjusted.     

Orlicz Algebras on Homogeneous Spaces of Compact Groups and Their Abstract Linear Representations

Let G be a compact group, H a closed subgroup of G and let m be the normalized G-invariant measure on the homogeneous space G / H obtained from Weil’s formula. In this article, for a given Young function \(\varphi \), we give a new class of Banach convolution algebras on homogeneous spaces of compact groups by introducing a convolution and an involution on the Orlicz space \(L^\varphi (G/H, m)\). Finally, a class of linear representations of this class of Banach convolution algebras is presented.     

Solution of Evolution Equation for Longitudinal Structure Function F L upto Next-to-Next-to-Leading Order and Its t-Evolution at Small-x

The aim of the present paper is to calculate longitudinal structure function F _L from QCD (Quantum Chromodynamics) evolution equation in next-to-next-to-leading order (NNLO) at small-x. The calculation of F _L is important for the phenomenological study of gluon distribution function inside the nucleon. Here we use Taylor Series Expansion method to solve the evolution equation for small-x and thus obtain t-evolution of F _L structure function. The calculated results are compared with H1 and ZEUS data and results of Block and Donnachie-Landshoff (DL) models.